Supercharging a 3-D Hybrid Supercapacitor with Graphene
By combining sheets of graphene with a traditional battery material, 
scientists have created hybrid supercapacitors that can store as much 
charge as lead acid batteries but can be recharged in seconds compared 
with hours for conventional batteries.
Now researchers at the University of California, Los Angeles, have 
developed a hybrid supercapacitor that is based on graphene, which is 
made of single layers of carbon atoms. Graphene is flexible, 
transparent, strong and electrically and thermally conductive, qualities
 that have led to research worldwide into whether the material could 
find use in advanced circuitry and other devices.
The scientists combined graphene with manganese dioxide, which is 
widely used in alkaline batteries and is both abundant and 
environmentally friendly. The manganese dioxide formed microscopic 
flowers made of flakes only 10 to 20 nanometers thick. The 
supercapacitors also incorporated electrolytes that can operate at high 
voltages.
                           
Significance
Batteries run just about 
everything portable in our lives such as smartphones, tablets, 
computers, etc. Although we have become
                              accustomed to the rapid improvement of 
portable electronics, the slow development of batteries is holding back 
technological
                              progress. Thus, it is imperative to 
develop new energy storage devices that are compact, reliable, and 
energy dense, charge
                              quickly, and possess both long cycle life 
and calendar life. Here, we developed hybrid supercapacitors that can 
store as much
                              charge as a lead acid battery, yet they 
can be recharged in seconds compared with hours for conventional 
batteries.
                           
 
Abstract
Supercapacitors now play an 
important role in the progress of hybrid and electric vehicles, consumer
 electronics, and military
                              and space applications. There is a growing
 demand in developing hybrid supercapacitor systems to overcome the 
energy density
                              limitations of the current generation of 
carbon-based supercapacitors. Here, we demonstrate 3D high-performance 
hybrid supercapacitors
                              and microsupercapacitors based on graphene
 and MnO
2 by rationally designing the electrode 
microstructure and combining active materials with electrolytes that 
operate at high
                              voltages. This results in hybrid 
electrodes with ultrahigh volumetric capacitance of over 1,100 F/cm
3. This corresponds to a specific capacitance of the constituent MnO
2
 of 1,145 F/g, which is close to the theoretical value of 1,380 F/g. The
 energy density of the full device varies between
                              22 and 42 Wh/l depending on the device 
configuration, which is superior to those of commercially available 
double-layer supercapacitors,
                              pseudocapacitors, lithium-ion capacitors, 
and hybrid supercapacitors tested under the same conditions and is 
comparable to
                              that of lead acid batteries. These hybrid 
supercapacitors use aqueous electrolytes and are assembled in air 
without the need
                              for expensive “dry rooms” required for 
building today’s supercapacitors. Furthermore, we demonstrate a simple 
technique for
                              the fabrication of supercapacitor arrays 
for high-voltage applications. These arrays can be integrated with solar
 cells for
                              efficient energy harvesting and storage 
systems